To pass the Salesforce ADM-201 Exam on the first attempt, start by thoroughly studying the Salesforce Administrator Exam Guide to understand key topics. Focus on areas such as user management, security, automation, and reporting. Leverage official Salesforce training resources like Trailhead modules and practice tests to reinforce learning. Hands-on experience with Salesforce is crucial, so practice using a real or developer account to apply concepts in a practical environment. Review mock exams and identify weak areas to target improvement. Time management and consistent revision of key concepts will help ensure success on the first attempt.